Title: Pre-versus post-main sequence evolutionary phase of B[e] stars Abstract: Many galactic B[e] stars suffer from improper distance determinations, which make it difficult to distinguish between a pre- and post-main sequence evolutionary phase on the basis of luminosity arguments. In addition, these stars have opaque circumstellar material, obscuring the central star, so that no detailed surface abundance studies can be performed. We propose a different indicator for the supergiant status of a B[e] star, based on the enrichment of its circumstellar matter by 13C, and detectable via its 13CO band emission in the K band spectra. Based on stellar evolution models, we calculate the variation of the 12C/13C isotopic surface abundance ratio during the evolution of massive stars. This ratio is found to decrease strongly during the post-main sequence evolution, from its interstellar value of about 70 to a value of about 15-20 for stars with initial masses higher than 7 M_sun, and to a value of less than 5 for stars with initial masses higher than 25 M_sun. We find that detectable 13CO band head emission is produced for isotope ratios 12C/13C < 20, and can easiest be detected with a spectral resolution of R ~ 1500. Such a resolution can be achieved with VLTI/AMBER in the K band, and some first test observations of the unclassified galactic B[e] star GG Car revealed the presence of detectable 13CO band emission, classifying GG Car as an evolved (i.e., supergiant) star.